Thin Films

Thin Films

The activities of the group are centered around thin film catalyst models. Such models mimic relevant aspects of a real world catalysts, but have a reduced complexity. That allows us to understand catalytic processes in detail. Central activities of the group are the development of thin film preparation recipes and the study of thermal and electrocatalytic reactions at the thin film / gas or liquid interfaces.

Supported catalysts may be mimicked by deposition of metallic aggregates. Several surface-sensitive experimental methods (XPS, TPD, STEM, EELS, IR surface action spectroscopy) are applied under vacuum conditions and at elevated pressures.

Group Members

Name Email
Dr. Afshan Jamshaid
Dr. Helmut Kuhlenbeck
Dr. Sotiris Tsatsos
Walter Wachsmann 
.

Research

SPM

SPM

Scanning probe microscopy is applied to investigate surface structures. Sometimes also X-ray based structural methods or I/V-LEED structural analysis may be used.

XPS

XPS

With XPS the elemental composition of the surface and the electronic structure of the surface atoms is investigated. This may also involve adsorbates and/or deposited aggregates.

HREELS

HREELS

HREELS is a method for the study of vibrations and electronic excitations at the surface. It may also reveal relevant information about deposited aggregates and adsorbates. In this method electrons are scattered inelastically at a surface. Hereby the electrons suffer an energy loss which is the desired information.

Action Spectroscopy

Action Spectroscopy

Surface action spectroscopy is a newly developed vibrational method. The investigated surface is covered with weakly bound atoms (the messengers) which are desorbed when infrared radiation [coming from the free electron laser (FEL) of the Institute] excites a vibration of the surface.

Recent Publications

2023
E. Davis, A. Bergmann, C. Zhan, H. Kuhlenbeck and B. Roldan Cuenya: Comparative study of Co3O4(111), CoFe2O4(111), and Fe3O4(111) thin film electrocatalysts for the oxygen evolution reaction. Nature Communications 14, 4791 (2023).
2022
Y. Liu, Z. Han, S. Gewinner, W. Schöllkopf, S.V. Levchenko, H. Kuhlenbeck and B. Roldan Cuenya: Adatom Bonding Sites in a Nickel-Fe3O4(001) Single-Atom Model Catalyst and O2 Reactivity Unveiled by Surface Action Spectroscopy with Infrared Free-Electron Laser Light. Angewandte Chemie International Edition 61 (28), e202202561 (2022).
2021
Y. Liu, Y. Peng, M. Naschitzki, S. Gewinner, W. Schöllkopf, H. Kuhlenbeck, R. Pentcheva and B. Roldan Cuenya: Surface oxygen Vacancies on Reduced Co3O4(100): Superoxide Formation and Ultra-Low-Temperature CO Oxidation. Angewandte Chemie International Edition 60 (30), 16514–16520 (2021).

Talks

2021
Kuhlenbeck, H.: Model Studies of Crystalline Thin Oxide Films: Surface Action Spectroscopy and Electrochemistry. FHI-Workshop on Current Research Topics at the FHI, Potsdam, Germany (2021)
2019
Kuhlenbeck, H.: High Resolution Electron Energy Loss Spectroscopy. IMPRS Fall Block Course 2019, Unifying Concepts in Spectroscopy, Berlin, Germany (2019)
Kuhlenbeck, H.: Surface Action Spectroscopy With Inert Gas Messengers. Seminar, Suzhou Institute of Nano-tech and Nano-bionics (SINANO), Chinese Academy of Sciences, Suzhou, China (2019)

Former Group Photos

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