Operando Hard X-ray Spectroscopy

Operando Hard X-ray Spectroscopy

Synchrotron radiation facilities are powerful X-ray sources that can be employed for numerous experimental techniques, including X-ray spectroscopic, scattering and imaging methods. The features of synchrotron radiation - high intensity and broad energy spectrum - make these sources ideally suited for in-situ and operando investigations of advanced materials.

Time-resolved operando X-ray absorption spectroscopy data are deciphered using machine learning methods to extract fingerprints of evolving structural motifs.

In the focus of our group's research is the application and development of complementary synchrotron radiation techniques (X-ray absorption spectroscopy, high-energy X-ray diffraction coupled with pair distribution function analysis, small-angle X-ray scattering) that provide information about the transformations of catalyst structure on different length and time scales under catalytically relevant conditions.

By combining unique synthesis methods, state-of-the art tools for experimental characterization and advanced approaches to data analysis, atomistic details of chemical and electrochemical reactions at gas/solid and liquid/solid interfaces are revealed, and structure-property relationship in these materials are established.

Group Members

Dr. Janis Timoshenko
Dr. Uta Hejral

Recent Publications

T. Möller, F. Scholten, T.N. Thanh, I. Sinev, J. Timoshenko, X. Wang, Z. Jovanov, M. Gliech, B. Roldan Cuenya, A.S. Varela and P. Strasser: Electrocatalytic CO2 Reduction on CuOx Nanocubes Tracking the Evolution of Chemical State, Geometric Structure, and Catalytic Selectivity using Operando Spectroscopy. Angewandte Chemie International Edition 59 (41), 17974–17983 (2020).
J. Timoshenko and B. Roldan Cuenya: In Situ/Operando Electrocatalyst Characterization by X-ray Absorption Spectroscopy. Chemical Reviews, in press.
S. Kunze, P. Grosse, M.B. Lopez, I. Sinev, I. Zegkinoglou, H. Mistry, J. Timoshenko, M.Y. Hu, J. Zhao, E.E. Alp, S.W. Chee and B. Roldan Cuenya: Operando NRIXS and XAFS Investigation of Segregation Phenomena in Fe‐Cu and Fe‐Ag Nanoparticle Catalysts during CO2 Electroreduction. Angewandte Chemie International Edition, in press.
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