Interfacial Ionics

Interfacial Ionics

Interfacial ionic processes are everywhere. Consider water dissociation (WD), H2O → H+ + OH-, which is required for every proton-coupled reaction in bio- and electrochemistry at alkaline to neutral pH (i.e. where the H+ comes from H2O). Despite its importance, WD is poorly understood and limits the efficiency of key technologies - in particular of water electrolysis generating green hydrogen and bipolar membranes producing acid and base solutions from green electricity.

Another example is ionic (de)solvation occurring during Li+ intercalation in Li-ion batteries. The (de)solvation is thought to be one reason why these batteries cannot be (dis)charged faster and why performance degrades at colder temperatures. Grotthuss transport, hydrogen spillover, dehydrogenation in organic chemistry, proton gradients and action potentials in biochemistry - interfacial ionics are ubiquitous, but our understanding has remained very limited.

In our laboratory, we study interfacial ionics at technologically-relevant, bipolar membrane and operational (electro)catalyst interfaces. We want to understand how molecules are dissociated and formed and ions are (de)solvated. What is the role of local electrostatics and local acid-base chemistry in tuning interfacial ionic processes? What are the differences between driving reactions ionically vs. electrically, and can this tell us something about the similarities and differences between electro- and thermal catalysis?

To that end, we employ existing, state-of-the-art electrochemistry and (electro)catalyst characterization, while also developing new operando methods to track ionic processes in time and space at a plethora of heterogeneous interfaces.





Group Members

Dr. Sebastian Öner

Group Leader

Dr. Mariana Cecilio de Oliveira Monteiro

Minerva Fast-Track Group Leader

Dr. Francisco Sarabia Gambin

Marie Curie Postdoctoral Fellow

Carlos Gomez Rodellar

PhD Student

Dr. Daniel Escalera-Lopez


Dr. Alex Ricardo Silva Olaya


Dr. José María Gisbert González


Hader Sinanovic

PhD Student

Recent Publications

Articles, peer-reviewed

H. Jeon, J. Timoshenko, C. Rettenmaier, A. Herzog, A. Yoon, S.W. Chee, S. Oener, U. Hejral, F. Haase and B. Roldan Cuenya: Selectivity control of Cu nanocrystals in a gas-fed flow cell through CO2 pulsed electroreduction. Journal of the American Chemical Society 143 (19), 7578–7587 (2021).

Articles, non peer-reviewed

B. Roldan Cuenya, A. Bergmann, C. Kley, P. Grosse and S. Oener: Klimaneutralität mittels Katalyse. Jahrbuch / Max-Planck-Gesellschaft 2020, 11659628 (2021).
B. Roldan Cuenya, A. Bergmann, C. Kley, P. Grosse and S. Oener: Maßgeschneiderte Katalysatoren für die grüne Energiewirtschaft. Highlights aus dem Jahrbuch der Max-Planck-Gesellschaft 2020, 8–10 (2021).
B. Roldan Cuenya, A. Bergmann, C. Kley, P. Grosse and S. Oener: Tailor-made catalysts for the green energy industry. Highlights from the yearbook of the Max Planck Society 2020, 8–10 (2021).
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