Fritz Haber Institute of the Max Planck Society

Publications

Publications

Interface Science Department since 2017

For a complete list of publications of the ISC-Director click here.

Journal Articles & Book Chapters

2023

M. Munz, J. Poon, W. Frandsen, B. Roldan Cuenya and C. Kley: Nanoscale Electron Transfer Variations at Electrocatalyst–Electrolyte Interfaces Resolved by in Situ Conductive Atomic Force Microscopy. Journal of the American Chemical Society 145 (9), 5242–5251 (2023).

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G. Wartner, D. Hein, A. Bergmann, R. Wendt, B. Roldan Cuenya and R. Seidel: Insights into the electronic structure of Fe-Ni thin-film catalysts during oxygen evolution reaction using operando resonant Photoelectron Spectroscopy. Journal of Materials Chemistry A, in press.

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C. Zhan, J. Yi, S. Hu, X.-G. Zhang, D.-Y. Wu and Z.-Q. Tian: Plasmon-mediated chemical reactions. Nature Reviews Methods primers 3 (1), 12 (2023).

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J. Timoshenko, F. Haase, S. Saddeler, M. Rüscher, H. Jeon, A. Herzog, U. Hejral, A. Bergmann, S. Schulz and B. Roldan Cuenya: Deciphering the Structural and Chemical Transformations of Oxide Catalysts during Oxygen Evolution Reaction Using Quick X-ray Absorption Spectroscopy and Machine Learning. Journal of the American Chemical Society 145 (7), 4065–4080 (2023).

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D. Kordus, J. Jelic, M. Lopez-Luna, Divins Núria J., J. Timoshenko, S.W. Chee, C. Rettenmaier, J. Kröhnert, S. Kühl, A. Trunschke, R. Schlögl, F. Studt and B. Roldan Cuenya: Shape-Dependent CO₂ Hydrogenation to Methanol over Cu₂O Nanocubes Supported on ZnO. Journal of the American Chemical Society, in press.

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H. Liu, J. Timoshenko, L. Bai, Q. Li, M. Rüscher, C. Sun, B. Roldan Cuenya and J. Luo: Low-Coordination Rhodium Catalysts for an Efficient Electrochemical Nitrate Reduction to Ammonia. ACS Catalysis 13 (2), 1513–1521 (2023).

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M. Munz, B. Roldan Cuenya and C. Kley: In Situ Investigation of Catalytic Interfaces by Scanning Probe Microscopy under Electrochemical Conditions. In: Encyclopedia of Solid-Liquid Interfaces. (Ed.): K. Wandelt. Elsevier, , in press.

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2022

M. Prieto, T. Mullan, W. Wan, L.C. Tanase, L.de S. Caldas, S.K. Shaikhutdinov, J. Sauer, D. Usvyat, T. Schmidt and B. Roldan Cuenya: Plasma Functionalization of Silica Bilayer Polymorphs. ACS Applied Materials and Interfaces 14 (43), 48609–48618 (2022).

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J.J. Navarro, M. Das, S. Tosoni, F. Landwehr, M. Heyde, G. Pacchioni, F. Glorius and B. Roldan Cuenya: Promoted Thermal Reduction of Copper Oxide Surfaces by N-Heterocyclic Carbenes. The Journal of Physical Chemistry C 126 (41), 17528–17535 (2022).

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J. Zeininger, P. Winkler, M. Raab, Y. Suchorski, M. Prieto, L.C. Tanase, L.de S. Caldas, A. Tiwari, T. Schmidt, M. Stöger-Pollach, A. Steiger-Thirsfeld, B. Roldan Cuenya and G. Rupprechter: Pattern Formation in Catalytic H₂ Oxidation on Rh: Zooming in by Correlative Microscopy. ACS Catalysis 12 (19), 11974–11983 (2022).

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S.W. Chee and B. Roldan Cuenya: 2022 Roadmap on Low Temperature Electrochemical CO₂ Reduction: Mechanistic insight into the electrocatalytic reduction of CO₂ via operando spectroscopy and microscopy methods. Journal of Physics: Energy 4 (4), 042003 (2022).

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J.J. Navarro, M. Das, S. Tosoni, F. Landwehr, J.P. Bruce, M. Heyde, G. Pacchioni, F. Glorius and B. Roldan Cuenya: Covalent Adsorption of N-Heterocyclic Carbenes on a Copper Oxide Surface. Journal of the American Chemical Society 144 (36), 16267–16271 (2022).

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R. Napier, B. Roldan Cuenya and M.T.M. Koper: The 2022 solar fuels roadmap: CO₂RR Catalysis: Surface Reactivity and Products Selectivity. Journal of Physics D 55 (32), 42–43 (2022).

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F. Haase, A. Bergmann, T. Jones, J. Timoshenko, A. Herzog, H. Jeon, C. Rettenmaier and B. Roldan Cuenya: Size effects and active state formation of cobalt oxide nanoparticles during the oxygen evolution reaction. Nature Energy 7 (8), 765–773 (2022).

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J.J. Navarro, M. Das , S. Tosoni, F. Landwehr, M. Koy, M. Heyde, G. Pacchioni, F. Glorius and B. Roldan Cuenya: Growth of N-Heterocyclic Carbene Assemblies on Cu(100) and Cu(111): from Single Molecules to Magic-Number Islands. Angewandte Chemie International Edition 61 (30), e202202127 (2022).

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A. Yoon, J. Poon, P. Grosse, S.W. Chee and B. Roldan Cuenya: Iodide-mediated Cu catalyst restructuring during CO₂ electroreduction. Journal of Materials Chemistry A 10 (26), 14041–14050 (2022).

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F. Haase, A. Rabe, F. Schmidt, A. Herzog, H. Jeon, W. Frandsen, P.V. Narangoda, I. Spanos, K.F. Ortega, J. Timoshenko, T. Lunkenbein, M. Behrens, A. Bergmann, R. Schlögl and B. Roldan Cuenya: Role of Nanoscale Inhomogeneities in Co₂FeO₄ Catalysts during the Oxygen Evolution Reaction. Journal of the American Chemical Society 144 (27), 12007–12019 (2022).

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Y. Liu, Z. Han, S. Gewinner, W. Schöllkopf, S.V. Levchenko, H. Kuhlenbeck and B. Roldan Cuenya: Adatom Bonding Sites in a Nickel-Fe₃O₄(001) Single-Atom Model Catalyst and O₂ Reactivity Unveiled by Surface Action Spectroscopy with Infrared Free-Electron Laser Light. Angewandte Chemie International Edition 61 (28), e202202561 (2022).

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E. Zschech, E. Topal, K. Kutukova, J. Gluch, M. Löffler, S. Werner, P. Guttmann, G. Schneider, Z. Liao and J. Timoshenko: Multi-scale microscopy study of 3D morphology and structure of MoNi₄/MoO₂@Ni electrocatalytic systems for fast water dissociation. Micron 158, 103262 (2022).

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J. Timoshenko: Spectroscopy predicts catalyst functionality. Nature Catalysis 5 (6), 469–470 (2022).

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N. Michalak, T. Ossowski, Z. Miłosz, M. Prieto, Y. Wang, M. Werwiński, V. Babacic, F. Genuzio, L. Vattuone, A. Kiejna, T. Schmidt and M. Lewandowski: Ostwald Ripening in an Oxide-on-Metal System. Advanced Materials Interfaces 9 (17), 2200222 (2022).

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H. Liu, X. Lang, C. Zhu, J. Timoshenko, M. Rüscher, L. Bai, N. Guijarro, H. Yin, Y. Peng, J. Li, Z. Liu, W. Wang, B. Roldan Cuenya and J. Luo: Efficient Electrochemical Nitrate Reduction to Ammonia with Copper supported Rhodium Cluster and Single-Atom Catalysts. Angewandte Chemie International Edition 61 (23), e202202556 (2022).

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S. Ott, F. Du, M. Lopez-Luna, T.A. Dao, S. Selve, B. Roldan Cuenya, A. Orfanidi and P. Strasser: Property-reactivity relations of N-doped PEM fuel cell cathode catalyst supports. Applied Catalysis B 306, 121118 (2022).

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S. Ott, F. Du, M. Lopez-Luna, T.A. Dao, B. Roldan Cuenya, A. Orfanidi and P. Strasser: Understanding the performance increase of catalysts supported on N-functionalized carbon in PEMFC catalyst layers. Journal of the Electrochemical Society 169 (5), 054520 (2022).

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W. Wan, J. Geiger, N. Berdunov, M. Lopez-Luna, S.W. Chee, N. Daelman, N. López, S.K. Shaikhutdinov and B. Roldan Cuenya: Highly Stable and Reactive Platinum Single Atoms on Oxygen Plasma-Functionalized CeO₂ Surfaces: Nanostructuring and Peroxo Effects. Angewandte Chemie International Edition 61 (20), e202112640 (2022).

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M. Rüscher, A. Herzog, J. Timoshenko, H. Jeon, W. Frandsen, S. Kühl and B. Roldan Cuenya: Tracking heterogeneous structural motifs and the redox behaviour of copper-zinc nanocatalysts for the electrocatalytic CO₂ reduction using operando time resolved spectroscopy and machine learning. Catalysis Science & Technology 12 (9), 3028–3043 (2022).

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J. Timoshenko, A. Bergmann, C. Rettenmaier, A. Herzog, R. Aran Ais, H. Jeon, F. Haase, U. Hejral, P. Grosse, S. Kühl, E. Davis, J. Tian, O. Magnussen and B. Roldan Cuenya: Steering the structure and selectivity of CO₂ electroreduction catalysts by potential pulses. Nature Catalysis 5 (4), 259–267 (2022).

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C. Li, W. Ju, S. Vijay, J. Timoshenko, K. Mou, D.A. Cullen, J. Yang, X. Wang, P. Pachfule, S. Brückner, H. Jeon, F. Haase, S.-C. Tsang, C. Rettenmaier, K. Chan, B. Roldan Cuenya, A. Thomas and P. Strasser: Covalent Organic Framework (COF) derived Ni-N-C Catalysts for Electrochemical CO₂ Reduction: Unraveling Fundamental Kinetic and Structural Parameters of the Active Sites. Angewandte Chemie International Edition 61 (15), e202114707 (2022).

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Ö. Akay, J. Poon, C. Robertson, F.F. Abdi, B. Roldan Cuenya, M. Giersig and K. Brinkert: Releasing the Bubbles: Nanotopographical Electrocatalyst Design for Efficient Photoelectrochemical Hydrogen Production in Microgravity Environment. Advanced Science 9 (8), 2105380 (2022).

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N. Daems, D. Choukroun, P. Merino, C. Rettenmaier, L. Pacquets, A. Bergmann, G. Santoro, L. Vázquez, L. Martínez, B. Roldan Cuenya, J.A. Martín Gago and T. Breugelmans: Steering Hydrocarbon Selectivity in CO₂ Electroreduction over Soft-Landed CuO_x Nanoparticle-Functionalized Gas Diffusion Electrodes. ACS Applied Materials and Interfaces 14 (2), 2691–2702 (2022).

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U. Hejral, J. Timoshenko, D. Kordus, M. Lopez-Luna, N.J. Divins, S. Widrinna, I. Zegkinoglou, L. Pielsticker, H. Mistry, J.A. Boscoboinik, S. Kühl and B. Roldan Cuenya: Tracking the phase changes in micelle-based NiGa nanocatalysts for methanol synthesis under activation and working conditions. Journal of Catalysis 405, 183–198 (2022).

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J. Poon, S.W. Chee, J. Timoshenko and B. Roldan Cuenya: Operando Studies of Electrocatalysts for Energy Technology Reactions. In: Operando Methods in Catalysis and Materials Science. (Eds.): B.M. Weckhuysen and A.-E. Nieuwelink. Willey-VCH, , in press.

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2021

X. Feng, H. Jena, C. Krishnaraj, D. Arenas-Esteban, K. Leus, G. Wang, J. Sun, M. Rüscher, J. Timoshenko, B. Roldan Cuenya, S. Bals and P. Van Der Voort: Creation of Exclusive Artificial Cluster Defects by Selective Metal Removal in the (Zn, Zr) Mixed-metal UiO-66. Journal of the American Chemical Society 143 (51), 21511–21518 (2021).

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S. Saddeler, G. Bendt, S. Salamon, F. Haase, J. Landers , J. Timoshenko, C. Rettenmaier, H. Jeon, A. Bergmann, H. Wende, B. Roldan Cuenya and S. Schulz: Influence of the cobalt content in cobalt iron oxides on the electrocatalytic OER activity. Journal of Materials Chemistry A 9 (45), 25381–25390 (2021).

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P. Grosse, A. Yoon, C. Rettenmaier, A. Herzog, S.W. Chee and B. Roldan Cuenya: Dynamic transformation of cubic copper catalysts during CO₂ electroreduction and its impact on catalytic selectivity. Nature Communications 12, 6736 (2021).

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S. Kunze, L.C. Tanase, M. Prieto, P. Grosse, F. Scholten, L.de S. Caldas, D. van Vörden, T. Schmidt and B. Roldan Cuenya: Plasma-assisted Oxidation of Cu(100) and Cu(111). Chemical Science 12 (42), 14241–14253 (2021).

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F. Scholten, K.-L.C. Nguyen, J.P. Bruce, M. Heyde and B. Roldan Cuenya: Identifying structure-selectivity correlations in the electrochemical reduction of CO₂: a comparison of well-ordered atomically-clean and chemically-etched Cu single crystal surfaces. Angewandte Chemie International Edition 60 (35), 19169–19175 (2021).

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H.I. Røst, B.P. Reed, F.S. Strand, J.A. Durk, A. Evans, A. Grubišić-Čabo, G. Wan, M. Cattelan, M. Prieto, D.M. Gottlob, L.C. Tanase, L.de S. Caldas, T. Schmidt, A. Tadich, B.C.C. Cowie, R.K. Chellappan, J.W. Wells and S.P. Cooil: A Simplified Method for Patterning Graphene on Dielectric Layers. ACS Applied Materials and Interfaces 13 (31), 37510–37516 (2021).

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Y. Liu, Y. Peng, M. Naschitzki, S. Gewinner, W. Schöllkopf, H. Kuhlenbeck, R. Pentcheva and B. Roldan Cuenya: Surface oxygen Vacancies on Reduced Co₃O₄(100): Superoxide Formation and Ultra-Low-Temperature CO Oxidation. Angewandte Chemie International Edition 60 (30), 16514–16520 (2021).

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C. Zhan, F. Dattila, C. Rettenmaier, A. Bergmann, S. Kühl, R. García-Muelas, N. Lopez and B. Roldan Cuenya: Revealing the CO Coverage Driven C-C Coupling Mechanism for Electrochemical CO₂ Reduction on Cu₂O Nanocubes via Operando Raman Spectroscopy. ACS Catalysis 11 (13), 7694–7701 (2021).

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J.P. Bruce, K.-L.C. Nguyen, F. Scholten, R. Aran Ais, J.J. Navarro, J. Hartmann, M. Heyde and B. Roldan Cuenya: Development of a single crystal sample holder for interfacing ultrahigh vacuum and electrochemical experimentation. Review of Scientific Instruments 92 (7), 074104 (2021).

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H. Jeon, J. Timoshenko, C. Rettenmaier, A. Herzog, A. Yoon, S.W. Chee, S. Oener, U. Hejral, F. Haase and B. Roldan Cuenya: Selectivity control of Cu nanocrystals in a gas-fed flow cell through CO₂ pulsed electroreduction. Journal of the American Chemical Society 143 (19), 7578–7587 (2021).

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M. Lopez-Luna, J. Timoshenko, D. Kordus, C. Rettenmaier, S.W. Chee, A.S. Hoffman, S.R. Bare, S.K. Shaikhutdinov and B. Roldan Cuenya: Role of the Oxide Support on the Structural and Chemical Evolution of Fe Catalysts during the Hydrogenation of CO₂. ACS Catalysis 11 (10), 6175–6185 (2021).

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S.W. Chee, T. Lunkenbein, R. Schlögl and B. Roldan Cuenya: In situ and operando electron microscopy in heterogeneous catalysis - insights into multi-scale chemical dynamics. Journal of Physics: Condensed Matter 33 (15), 153001 (2021).

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M. Homann, B. von Boehn, M. Prieto, D.M. Gottlob, L.C. Tanase, T. Schmidt, F. Genuzio, T.O. Menteş, A. Locatelli and R. Imbihl: Coupling of morphological instability and kinetic instability: Chemical waves in hydrogen oxidation on a bimetallic Ni/Rh(111) surface. Physical Review Materials 5 (4), 045002 (2021).

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A. Herzog, A. Bergmann, H. Jeon, J. Timoshenko, S. Kühl, C. Rettenmaier, M. Lopez-Luna, F. Haase and B. Roldan Cuenya: Operando Investigation of Ag‐Decorated Cu₂O Nanocube Catalysts with Enhanced CO₂ Electroreduction toward Liquid Products. Angewandte Chemie International Edition 60 (13), 7426–7435 (2021).

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L. Pielsticker, I. Zegkinoglou, Z.-K. Han, J.J. Navarro, S. Kunze, O. Karslıoğlu, S.V. Levchenko and B. Roldan Cuenya: Crystallographic Orientation Dependence of Surface Segregation and Alloying on PdCu Catalysts for CO₂ Hydrogenation. The Journal of Physical Chemistry Letters 12 (10), 2570–2575 (2021).

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N.J. Divins, D. Kordus, J. Timoshenko, I. Sinev, I. Zegkinoglou, A. Bergmann, S.W. Chee, S. Widrinna, O. Karslıoğlu, H. Mistry, M. Lopez Luna, J.Q. Zhong, A.S. Hoffmann, A. Boubnov, J.A. Boscoboinik, M. Heggen, R.E. Dunin-Borkowski, S.R. Bare and B. Roldan Cuenya: Operando high-pressure investigation of size-controlled CuZn catalysts for the methanol synthesis reaction. Nature Communications 12, 1435 (2021).

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O. Lupan, N. Magariu, R. Khaledialidusti, A. Mishra, S. Hansen, H. Krüger, V. Postica, H. Heinrich, B. Viana, L. Ono, B. Roldan Cuenya, L. Chow, R. Adelung and T. Pauporte: Comparison of Thermal Annealing versus Hydrothermal Treatment Effects on the Detection Performances of ZnO Nanowires. ACS Applied Materials and Interfaces 13 (8), 10537–10552 (2021).

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V. Ulrich, B. Moroz, P. Pyrjaev, I. Sinev, A. Bukhtiyarov, E. Gerasimov, V. Bukhtiyarov, B. Roldan Cuenya and W. Grünert: Three-way catalysis with bimetallic supported Pd-Au catalysts: Gold as a poison and as a promotor. Applied Catalysis B 282, 119614 (2021).

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H.I. Røst, R.K. Chellappan, F.S. Strand, Grubišić-Čabo Antonija, B.P. Reed, M. Prieto, L.C. Tanase, L.de S. Caldas, T. Wongpinij, C. Euaruksakul, T. Schmidt, A. Tadich, B.C.C. Cowie, Z. Li, S.P. Cooil and J.W. Wells: Low-Temperature Growth of Graphene on a Semiconductor. The Journal of Physical Chemistry C 125 (7), 4243–4252 (2021).

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G.H. Simon, C. Kley and B. Roldan Cuenya: Potential‐Dependent Morphology of Copper Catalysts During CO₂ Electroreduction Revealed by In Situ Atomic Force Microscopy. Angewandte Chemie International Edition 60 (5), 2561–2568 (2021).

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A. Yoon, A. Herzog, P. Grosse, D.H. Alsem, S.W. Chee and B. Roldan Cuenya: Dynamic Imaging of Nanostructures in an Electrolyte with a Scanning Electron Microscope. Microscopy and Microanalysis 27 (1), 121–128 (2021).

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J. Timoshenko and B. Roldan Cuenya: In Situ/Operando Electrocatalyst Characterization by X-ray Absorption Spectroscopy. Chemical Reviews 121 (2), 882–961 (2021).

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J.Q. Zhong, S.K. Shaikhutdinov and B. Roldan Cuenya: Structural Evolution of Ga-Cu Model Catalysts for CO₂ Hydrogenation Reactions. The Journal of Physical Chemistry C 125 (2), 1361–1367 (2021).

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R. Rizo, A. Bergmann, J. Timoshenko, F. Scholten, C. Rettenmaier, H. Jeon, Y.-T. Chen, A. Yoon, A. Bagger, J. Rossmeisl and B. Roldan Cuenya: Pt-Sn-Co nanocubes as highly active catalysts for ethanol electro-oxidation. Journal of Catalysis 393, 247–258 (2021).

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2020

C. Rettenmaier, R. Aran Ais, J. Timoshenko, R. Rizo, H. Jeon, S. Kühl, S.W. Chee, A. Bergmann and B. Roldan Cuenya: Enhanced Formic Acid Oxidation over SnO₂-decorated Pd Nanocubes. ACS Catalysis 10 (24), 14540–14551 (2020).

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P. Grosse, A. Yoon, C. Rettenmaier, S.W. Chee and B. Roldan Cuenya: Growth Dynamics and Processes Governing the Stability of Electrodeposited Size-Controlled Cubic Cu Catalysts. The Journal of Physical Chemistry C 124 (49), 26908–26915 (2020).

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S. Kunze, P. Grosse, M.B. Lopez, I. Sinev, I. Zegkinoglou, H. Mistry, J. Timoshenko, M.Y. Hu, J. Zhao, E.E. Alp, S.W. Chee and B. Roldan Cuenya: Operando NRIXS and XAFS Investigation of Segregation Phenomena in Fe‐Cu and Fe‐Ag Nanoparticle Catalysts during CO₂ Electroreduction. Angewandte Chemie International Edition 59 (50), 22667–22674 (2020).

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J. Halldin Stenlid, E. Campos dos Santos, R. Aran Ais, A. Bagger, A.J. Johansson, B. Roldan Cuenya, J. Rossmeisl and L.G.M. Pettersson: Uncovering the electrochemical interface of low-index copper surfaces in deep groundwater environments. Electrochimica Acta 362, 137111 (2020).

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D. Hein, G. Wartner, A. Bergmann, M. Bernal, B. Roldan Cuenya and R. Seidel: Reversible Water-Induced Phase Changes of Cobalt Oxide Nanoparticles. ACS Nano 14 (11), 15450–15457 (2020).

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H.N. Nong, L. Falling, A. Bergmann, M. Klingenhof, H.P. Tran, C. Spöri, R. Mom, J. Timoshenko, G. Zichittella, A. Knop-Gericke, S. Piccinin, J. Pérez-Ramírez, B. Roldan Cuenya, R. Schlögl, P. Strasser, D. Teschner and T. Jones: Key role of chemistry versus bias in electrocatalytic oxygen evolution. Nature 587 (7834), 408–413 (2020).

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K.J. Puring, O. Evers, M. Prokein, D. Siegmund, F. Scholten, N. Mölders, M. Renner, B. Roldan Cuenya, M. Petermann, E. Weidner and U.-P. Apfel: Assessing the Influence of Supercritical Carbon Dioxide on the Electrochemical Reduction to Formic Acid Using Carbon-Supported Copper Catalysts. ACS Catalysis 10 (21), 12783–12789 (2020).

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F. Franco, C. Rettenmaier, H. Jeon and B. Roldan Cuenya: Transition metal-based catalysts for the electrochemical CO₂ reduction: from atoms and molecules to nanostructured materials. Chemical Society Reviews 49 (19), 6884–6946 (2020).

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T. Möller, F. Scholten, T.N. Thanh, I. Sinev, J. Timoshenko, X. Wang, Z. Jovanov, M. Gliech, B. Roldan Cuenya, A.S. Varela and P. Strasser: Electrocatalytic CO₂ Reduction on CuO_x Nanocubes: Tracking the Evolution of Chemical State, Geometric Structure, and Catalytic Selectivity using Operando Spectroscopy. Angewandte Chemie International Edition 59 (41), 17974–17983 (2020).

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J. Velasco Vélez, C.-H. Chuang, D. Gao, Q. Zhu, D. Ivanov, H.S. Jeon, R. Arrigo, R. Mom, E. Stotz, H.-L. Wu, T. Jones, B. Roldan Cuenya, A. Knop-Gericke and R. Schlögl: On the Activity/Selectivity and Phase Stability of Thermally Grown Copper Oxides during the Electrocatalytic Reduction of CO₂. ACS Catalysis 10 (19), 11510–11518 (2020).

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J.J. Navarro, S. Tosoni, J.P. Bruce, L. Chaves, M. Heyde, G. Pacchioni and B. Roldan Cuenya: The Structure of a Silica Thin Film on Oxidized Cu(111): Conservation of Honeycomb Lattice and Role of the Interlayer. The Journal of Physical Chemistry C 124 (38), 20942–20949 (2020).

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R. Aran Ais, R. Rizo, P. Grosse, G. Algara-Siller, K. Dembélé, M. Plodinec, T. Lunkenbein, S.W. Chee and B. Roldan Cuenya: Imaging electrochemically synthesized Cu₂O cubes and their morphological evolution under conditions relevant to CO₂ electroreduction. Nature Communications 11, 3489 (2020).

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J. Velasco Velez, R. Mom, L. Sandoval Diaz, L. Falling, C.-H. Chuang, D. Gao, T. Jones, Q. Zhu, R. Arrigo, B. Roldan Cuenya, A. Knop-Gericke, T. Lunkenbein and R. Schlögl: Revealing the Active Phase of Copper during the Electroreduction of CO₂ in Aqueous Electrolyte by Correlating In Situ X-ray Spectroscopy and In Situ Electron Microscopy. ACS Energy Letters 5 (6), 2106–2111 (2020).

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F. Silvestri, M. Prieto, A. Babuji, L.C. Tanase, L.de S. Caldas, O. Solomeshch, T. Schmidt, C. Ocal and E. Barrena: Impact of Nanomorphology on Surface Doping of Organic Semiconductors: The Pentacene-C₆₀F₄₈ Interface. ACS Applied Materials and Interfaces 12 (22), 25444–25452 (2020).

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F. Dionigi, Z. Zeng, I. Sinev, T. Merzdorf, S. Deshpande, M.B. Lopez, S. Kunze, I. Zegkinoglou, H. Sarodnik, D. Fan, A. Bergmann, J. Drnec, J.F.D. Araujo, M. Gilech, D. Teschner, J. Zhu, W. Li, J.P. Greeley, B. Roldan Cuenya and P. Strasser: In-situ structure and catalytic mechanism of NiFe and CoFe layered double hydroxides during oxygen evolution. Nature Communications 11, 2522 (2020).

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K. Schweinar, S. Beeg, C. Hartwig, C.R. Rajamathi, O. Kasian, S. Piccinin, M. Prieto, L.C. Tanase, D.M. Gottlob, T. Schmidt, D. Raabe, R. Schlögl, B. Gault, T. Jones and M.T. Greiner: Formation of a 2D Meta-stable Oxide by Differential Oxidation of AgCu Alloys. ACS Applied Materials and Interfaces 12 (20), 23595–23605 (2020).

MPG.PuRe

publisher-version

J. Timoshenko, H. Jeon, I. Sinev, F. Haase, A. Herzog and B. Roldan Cuenya: Linking the evolution of catalytic properties and structural changes in copper-zinc nanocatalysts using operando EXAFS and neural-networks. Chemical Science 11 (14), 3727–3736 (2020).

MPG.PuRe

publisher-version

B. Eggert, M.E. Gruner, K. Ollefs, E. Schuster, N. Rothenbach, M.Y. Hu, J. Zhao, T.S. Toellner, W. Sturhahn, R. Pentcheva, B. Roldan Cuenya, E.E. Alp, H. Wende and W. Keune: Interface-related magnetic and vibrational properties in Fe/MgO heterostructures from nuclear resonant spectroscopy and first-principles calculations. Physical Review Materials 4 (4), 044402 (2020).

MPG.PuRe

publisher-version

R.M. Aran-Ais, F. Scholten, S. Kunze, R. Rizo and B. Roldan Cuenya: The role of in situ generated morphological motifs and Cu(I) species in C₂₊ product selectivity during CO₂ pulsed electroreduction. Nature Energy 5 (4), 317–325 (2020).

MPG.PuRe

S. Anke, T. Falk, G. Bendt, I. Sinev, M. Hävecker, H. Antoni, I. Zegkinoglou, H. Jeon, A. Knop-Gericke, R. Schlögl, B. Roldan Cuenya, S. Schulz and M. Muhler: On the reversible deactivation of cobalt ferrite spinel nanoparticles applied in selective 2-propanol oxidation. Journal of Catalysis 382, 57–68 (2020).

MPG.PuRe

2019

H. Jeon, J. Timoshenko, F. Scholten, I. Sinev, A. Herzog, F. Haase and B. Roldan Cuenya: Operando Insight into the Correlation between the Structure and Composition of CuZn Nanoparticles and their Selectivity for the Electrochemical CO₂ Reduction. Journal of the American Chemical Society 141 (50), 19879–19887 (2019).

MPG.PuRe

publisher-version

A. Bagger, R. Aran Ais, J.H. Stenlid, E.C.dos Santos, L. Arnarson, K.D. Jensen, M. Escudero-Escribano, B. Roldan Cuenya and J. Rossmeisl: Ab Initio Cyclic Voltammetry on Cu(111), Cu(100) and Cu(110) in Acidic, Neutral and Alkaline Solutions. ChemPhysChem 20 (22), 3096–3105 (2019).

MPG.PuRe

D. Gao, I. Sinev, F. Scholten, R. Aran Ais, N.J. Divins, K. Kvashnina, J. Timoshenko and B. Roldan Cuenya: Selective CO₂ Electroreduction to Ethylene and Multicarbon Alcohols via Electrolyte-Driven Nanostructuring. Angewandte Chemie International Edition 58 (47), 17047–17053 (2019).

MPG.PuRe

publisher-version

A. Bergmann and B. Roldan Cuenya: Operando Insights into Nanoparticle Transformations during Catalysis. ACS Catalysis 9 (11), 10020–10043 (2019).

MPG.PuRe

publisher-version

J. Timoshenko and A.I. Frenkel: “Inverting” X-ray Absorption Spectra of Catalysts by Machine Learning in Search for Activity Descriptors. ACS Catalysis 9 (11), 10192–10211 (2019).

MPG.PuRe

J. Timoshenko, M. Ahmadi and B. Roldan Cuenya: Is There a Negative Thermal Expansion in Supported Metal Nanoparticles? An in Situ X-ray Absorption Study Coupled with Neural Network Analysis. The Journal of Physical Chemistry C 123 (33), 20594–20604 (2019).

MPG.PuRe

publisher-version

F. Novelli, M.B. Lopez, G. Schwaab, B. Roldan Cuenya and M. Havenith: Water Solvation of Charged and Neutral Gold Nanoparticles. The Journal of Physical Chemistry B 123 (30), 6521–6528 (2019).

MPG.PuRe

M.V. Evers, M. Bernal, B. Roldan Cuenya and K. Tschulik: Piece by Piece-Electrochemical Synthesis of Individual Nanoparticles and their Performance in ORR Electrocatalysis. Angewandte Chemie International Edition 58 (24), 8221–8225 (2019).

MPG.PuRe

S. Anke, G. Bendt, I. Sinev, H.R. Hajiyani, H. Antoni, I. Zegkinoglou, H. Jeon, R. Pentcheva, B. Roldan Cuenya, S. Schulz and M. Muhler: Selective 2-Propanol Oxidation over Unsupported Co₃O₄ Spinel Nanoparticles: Mechanistic Insights into Aerobic Oxidation of Alcohols. ACS Catalysis 9 (7), 5974–5985 (2019).

MPG.PuRe

R. Rizo Parraga and B. Roldan Cuenya: Shape-Controlled Nanoparticles as Anodic Catalysts in Low Temperature Fuel Cells. ACS Energy Letters 4 (6), 1484–1495 (2019).

MPG.PuRe

publisher-version

F. Scholten, I. Sinev, M. Bernal and B. Roldan Cuenya: Plasma-Modified Dendritic Cu Catalyst for CO₂ Electroreduction. ACS Catalysis 9 (6), 5496–5502 (2019).

MPG.PuRe

publisher-version

M. Ahmadi, J. Timoshenko, F. Behafarid and B. Roldan Cuenya: Tuning the Structure of Pt Nanoparticles through Support Interactions: An In Situ Polarized X-ray Absorption Study Coupled with Atomistic Simulations. The Journal of Physical Chemistry C 123 (16), 10666–10676 (2019).

MPG.PuRe

publisher-version

I. Zegkinoglou, L. Pielsticker, Z.-K. Han, N.J. Divins, D. Kordus, Y.-T. Chen, C. Escudero, V. Pérez-Dieste, B. Zhu, Y. Gao and B. Roldan Cuenya: Surface Segregation in CuNi Nanoparticle Catalysts During CO₂ Hydrogenation: The Role of CO in the Reactant Mixture. The Journal of Physical Chemistry C 123 (13), 8421–8428 (2019).

MPG.PuRe

publisher-version

Y.-W. Choi, F. Scholten, I. Sinev and B. Roldan Cuenya: Enhanced Stability and CO/Formate Selectivity of Plasma-Treated SnO_x/AgO_x Catalysts during CO₂ Electroreduction. Journal of the American Chemical Society 141 (13), 5261–5266 (2019).

MPG.PuRe

publisher-version

C. Alvarez-Galvan, M. Melian, L. Ruiz-Matas, J.L. Eslava, R.M. Navarro, M. Ahmadi, B. Roldan Cuenya and J.L.G. Fierro: Partial Oxidation of Methane to Syngas Over Nickel-Based Catalysts: Influence of Support Type, Addition of Rhodium, and Preparation Method. Frontiers in Chemistry 7, 104 (2019).

MPG.PuRe

publisher-version

D. Gao, R. Aran Ais, H. Jeon and B. Roldan Cuenya: Rational catalyst and electrolyte design for CO₂ electroreduction towards multicarbon products. Nature Catalysis 2 (3), 198–210 (2019).

MPG.PuRe

S. Piontek, K.junge Puring, D. Siegmund, M. Smialkowski, I. Sinev, D. Tetzlaff, B. Roldan Cuenya and U.-P. Apfel: Bio-inspired design: bulk iron–nickel sulfide allows for efficient solvent-dependent CO₂ reduction. Chemical Science 10 (4), 1075–1081 (2019).

MPG.PuRe

publisher-version

supplementary-material

J. Velasco Vélez, T. Jones, D. Gao, E. Carbonio, R. Arrigo, C.-J. Hsu, Y.-C. Huang, C.L. Dong, J.-M. Chen, J.-F. Lee, P. Strasser, B. Roldan Cuenya, R. Schlögl, A. Knop-Gericke and C.-H. Chuang: The Role of the Copper Oxidation State in the Electrocatalytic Reduction of CO₂ into Valuable Hydrocarbons. ACS Sustainable Chemistry & Engineering 7 (1), 1485–1492 (2019).

MPG.PuRe

supplementary-material

J. Masa, C. Andronescu, H. Antoni, I. Sinev, S. Seisel, K. Elumeeva, S. Barwe, S. Marti-Sanchez, J. Arbiol, B. Roldan Cuenya, M. Muhler and W. Schuhmann: Role of Boron and Phosphorus in Enhanced Electrocatalytic Oxygen Evolution by Nickel Borides and Nickel Phosphides. ChemElectroChem 6 (1), 235–240 (2019).

MPG.PuRe

M. Koper and B. Roldan Cuenya: Electrochemical CO₂ reduction. In: Research needs towards sustainable production of fuels and chemicals. Energy-X, Grenoble, 19–27 (2019).

MPG.PuRe

2018

E. Özer, I. Sinev, A.M. Mingers, J. Araujo, T. Kropp, M. Mavrikakis, K.J.J. Mayrhofer, B. Roldan Cuenya and P. Strasser: Ir–Ni Bimetallic OER Catalysts Prepared by Controlled Ni Electrodeposition on Ir_poly and Ir(111). Surfaces 1 (1), 165–186 (2018).

MPG.PuRe

publisher-version

V. Ulrich, C. Froese, B. Moroz, P. Pyrjaev, E. Gerasimov, I. Sinev, B. Roldan Cuenya, M. Muhler, V. Bukhtiyarov and W. Grünert: Three-way catalysis with supported gold catalysts: Poisoning effects of hydrocarbons. Applied Catalysis B 237, 1021–1032 (2018).

MPG.PuRe

Y. Dong, O. Korup, J. Gerdts, B. Roldan Cuenya and R. Horn: Microtomography-based CFD modeling of a fixed-bed reactor with an open-cell foam monolith and experimental verification by reactor profile measurements. Chemical Engineering Journal 353, 176–188 (2018).

MPG.PuRe