Publications 2022 of the Inorganic Chemistry Department

Journal Article

Arrigo, R., R. Blume, V. Streibel, C. Genovese, A. Roldan, M.E. Schuster, C. Ampelli, S. Perathoner, J. Velasco Vélez, M. Hävecker, A. Knop-Gericke, R. Schlögl and G. Centi: Dynamics at Polarized Carbon Dioxide-Iron Oxyhydroxide Interfaces Unveil the Origin of Multicarbon Product Formation. ACS Catalysis 12 (1), 411–430 (2022).

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Journal Article

Brooks, A., S.J. Jenkins, S. Wrabetz, J. McGregor and M. Sacchi: The dehydrogenation of butane on metal-free graphene. Journal of Colloid and Interface Science 619, 377–387 (2022).

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Journal Article

Carlomagno, I., P. Zeller, M. Amati, G. Aquilanti, E. Prenesti, G. Marussi, G. Crosera and M. Adami: Combining synchrotron radiation techniques for the analysis of gold coins from the Roman Empire. Scientific Reports 12 (1), 15919 (2022).

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Journal Article

Chen, D., M. Barreau, S. Turczyniak-Surdacka c, K. Sobczak, M. Strawski, A.L.G.L. Salle, A. Efimenko, D. Teschner, C. Petit and S. Zafeiratos: Ceria nanoparticles as promoters of CO₂ electroreduction on Ni/YSZ: An efficient preparation strategy and insights into the catalytic promotion mechanism. Nano Energy 101, 107564 (2022).

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supplementary-material

Journal Article

Choudhury, S.H., Y. Ding, Y. Yi, C. Rohner, W. Frandsen, T. Lunkenbein, M. Greiner, R. Schlögl and S. Heumann: Oxidation Behavior of Glassy Carbon in Acidic Electrolyte. ChemElectroChem 9 (20), e202200637 (2022).

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Journal Article

Cirera, B., Y. Litman, C. Lin, A. Akkoush, A. Hammud, M. Wolf, M. Rossi and T. Kumagai: Charge Transfer-Mediated Dramatic Enhancement of Raman Scattering upon Molecular Point Contact Formation. Nano Letters 22 (6), 2170–2176 (2022).

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Journal Article

Codeço, C.F.S., A. Klyushin, E. Carbonio, A. Knop-Gericke, R. Schlögl, T. Jones and T.C.R. Rocha: Insights into the electronic structure of hydroxyl on Ag(110) under near ambient conditions. Physical Chemistry Chemical Physics 24 (15), 8832–8838 (2022).

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Journal Article

Cui, W., Y. Xu, G. Luo, Q. Zhang and Z. Li: Simultaneous catalytic oxidation of nitric oxide and elemental mercury over Cu-Fe binary oxide treated by oxygen non-thermal plasma. Fuel 330, 123895 (2022).

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Journal Article

Dupuy, R., J. Filser, C. Richter, R. Seidel, F. Trinter, T. Buttersack, C. Nicolas, J. Bozek, U. Hergenhahn, H. Oberhofer, B. Winter, K. Reuter and H. Bluhm: Photoelectron angular distributions as sensitive probes of surfactant layer structure at the liquid-vapor interface. Physical Chemistry Chemical Physics 24 (8), 4796–4808 (2022).

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Journal Article

Folke, J., K. Dembélé, F. Girgsdies, H. Song, R. Eckert, S. Reitmeier, A. Reitzmann, R. Schlögl, T. Lunkenbein and H. Ruland: Promoter effect on the reduction behavior of wuestite-based catalysts for ammonia synthesis. Catalysis Today 387, 12–22 (2022).

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Journal Article

Ghafari, A., W. Khan and C. Janowitz: Electronic structure and engineered thermoelectric properties of SnSe. Physica B 630, 413668 (2022).

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Journal Article

Ghampson, I.T., S.-T.B. Lundin, V. Vargheese, Y. Kobayashi, G. Huff, R. Schlögl, A. Trunschke and S.T. Oyama: Methane selective oxidation on metal oxide catalysts at low temperatures with O₂ using an NO/NO₂ oxygen atom shuttle. Journal of Catalysis 408, 401–412 (2022).

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supplementary-material

Journal Article

Giusto, P., D. Cruz, Y. Rodriguez, R. Rothe and N.V. Tarakina: Red Carbon Thin Film: A Carbon-Oxygen Semiconductor with Tunable Properties by Amine Vapors and Its Carbonization toward Carbon Thin Films. Advanced Materials Interfaces 9 (21), 2200834 (2022).

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Journal Article

Giusto, P., B. Kumru, D. Cruz and M. Antonietti: Optical Anisotropy of Carbon Nitride Thin Films and Photografted Polystyrene Brushes. Advanced Optical Materials 10 (4), 2101965 (2022).

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Journal Article

Grünleitner, T., A. Henning, M. Bissolo, M. Zengerle, L. Gregoratti, M. Amati, P. Zeller, J. Eichhorn, A.V. Stier, A.W. Holleitner, J.J. Finley and I.D. Sharp: Real-Time Investigation of Sulfur Vacancy Generation and Passivation in Monolayer Molybdenum Disulfide via in situ X-ray Photoelectron Spectromicroscopy. ACS Nano 16 (12), 20364–20375 (2022).

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Journal Article

Haase, F., A. Bergmann, T. Jones, J. Timoshenko, A. Herzog, H. Jeon, C. Rettenmaier and B. Roldan Cuenya: Size effects and active state formation of cobalt oxide nanoparticles during the oxygen evolution reaction. Nature Energy 7 (8), 765–773 (2022).

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Journal Article

Haase, F., A. Rabe, F. Schmidt, A. Herzog, H. Jeon, W. Frandsen, P.V. Narangoda, I. Spanos, K.F. Ortega, J. Timoshenko, T. Lunkenbein, M. Behrens, A. Bergmann, R. Schlögl and B. Roldan Cuenya: Role of Nanoscale Inhomogeneities in Co₂FeO₄ Catalysts during the Oxygen Evolution Reaction. Journal of the American Chemical Society 144 (27), 12007–12019 (2022).

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Journal Article

Hauser, D., C. Grießer, E.-M. Wernig, T. Götsch, J. Bernardi, J. Kunze-Liebhäuser and S. Penner: The pervasive presence of oxygen in ZrC. Surfaces and Interfaces 34, 102373 (2022).

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Journal Article

Hegen, O., J.I.S. Gómez, C. Grünwald, A. Rettke, M. Sojka, C. Klucken, J. Pickenbrock, J. Filipp, R. Schlögl and H. Ruland: Bridging the Analytical Gap Between Gas Treatment and Reactor Plants in Carbon2Chem_®. Chemie-Ingenieur-Technik 94 (10), 1405–1412 (2022).

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Journal Article

Hermann, K.: Structure of Polyhedral Nanoparticles with Cubic Lattice: Theoretical Analysis. International Journal of Nanoscience 21 (3), 2250010 (2022).

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pre-print

Journal Article

Javed, H., A. Knop-Gericke and R.V. Mom: Structural Model for Transient Pt Oxidation during Fuel Cell Start-up Using Electrochemical X-ray Photoelectron Spectroscopy. ACS Applied Materials and Interfaces 14 (31), 36238–36245 (2022).

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Journal Article

Junker, B., M. Favaro, D.E. Starr, M. Hävecker, U. Weimar and N. Barsan: NAP-XPS as a new tool for in-situ studies of SMOX gas sensors. Journal of Physics D 55 (6), 064002 (2022).

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Journal Article

Kang, S., C. Im, I. Spanos, K. Ham, A. Lim, T. Jacob, R. Schlögl and J. Lee: Durable Nickel-Iron (Oxy)hydroxide Oxygen Evolution Electrocatalysts through Surface Functionalization with Tetraphenylporphyrin. Angewandte Chemie International Edition 61 (51), e202214541 (2022).

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Journal Article

Kang, S., C. Im, I. Spanos, K. Ham, A. Lim, T. Jacob, R. Schlögl and J. Lee: Durable Nickel-Iron (Oxy)hydroxide Oxygen Evolution Electrocatalysts through Surface Functionalization with Tetraphenylporphyrin. Angewandte Chemie 134 (51), e202214541 (2022).

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Journal Article

Karslıoğlu, O., L. Trotochaud, F. Salmassi, E.M. Gullikson, A. Shavorskiy, S. Nemšák and H. Bluhm: Prospects for the expansion of standing wave ambient pressure photoemission spectroscopy to reactions at elevated temperatures. Journal of Vacuum Science and Technology A 40 (1), 013207 (2022).

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Journal Article

Kenmoe, S., D.H. Douma, A.T. Raji, B. M’Passi-Mabiala, T. Götsch, F. Girgsdies, A. Knop-Gericke, R. Schlögl and E. Spohr: X-ray Absorption Near-Edge Structure (XANES) at the O K-Edge of Bulk Co₃O₄: Experimental and Theoretical Studies. Nanomaterials 12 (6), 921 (2022).

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Journal Article

Kim, J.Y., S. Chae, W. Jang, Q.A. Besford, J.Y. Oh and T.I. Lee: Antioxidant Triggered Metallic 1T’ Phase Transformations of Chemically Exfoliated Tungsten Disulfide (WS₂) Nanosheets. Small 18 (12), 2107557 (2022).

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Journal Article

Klingenhof, M., P. Hauke, M. Kroschel, X. Wang, T. Merzdorf, C. Binninger, T.N. Thanh, B. Paul, D. Teschner, R. Schlögl and P. Strasser: Anion-Tuned Layered Double Hydroxide Anodes for Anion Exchange Membrane Water Electrolyzers: From Catalyst Screening to Single-Cell Performance. ACS Energy Letters 7 (10), 3415–3422 (2022).

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Journal Article

Köwitsch, N., S. Barth, K. Ploner, R. Blume, D. Teschner, S. Penner and M. Armbrüster: Properties of Bulk In-Pt Intermetallic Compounds in Methanol Steam Reforming. ChemPhysChem 23 (8), e202200074 (2022).

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Journal Article

Kraus, P., E. Wolf, C. Prinz, G. Bellini, A. Trunschke and R. Schlögl: Towards automation of operando experiments: A case study in contactless conductivity measurements. Digital Discovery 1 (3), 241–254 (2022).

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pre-print

Journal Article

Kube, P., J. Dong, N. Sánchez Bastardo, H. Ruland, R. Schlögl, J. Margraf, K. Reuter and A. Trunschke: Green synthesis of propylene oxide directly from propane. Nature Communications 13, 7504 (2022).

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Journal Article

Li, Z., S. Li, J.-P. Castellan, R. Heid, Y. Xiao, L.-D. Zhao, Y. Chen and F. Weber: Anomalous transverse optical phonons in SnTe and PbTe. Physical Review B 105 (1), 014308 (2022).

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Journal Article

Li, Z., R. Zou, Y. Xu, Y. Fang, G. Luo and H. Yao: Characterization of in-situ and cooling char from ten typical Chinese coals. Combustion and Flame 238, 111884 (2022).

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Journal Article

Lin, Y., L. Yu, L. Tang, F. Song, R. Schlögl and S. Heumann: In Situ Identification and Time-Resolved Observation of the Interfacial State and Reactive Intermediates on a Cobalt Oxide Nanocatalyst for the Oxygen Evolution Reaction. ACS Catalysis 12 (9), 5345–5355 (2022).

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Journal Article

Lipp, J., R. Banerjee, M.F. Patwary, N. Patra, A. Dong, F. Girgsdies, S.R. Bare and J.R. Regalbuto: Extension of Rietveld Refinement for Benchtop Powder XRD Analysis of Ultrasmall Supported Nanoparticles. Chemistry of Materials 34 (18), 8091–8111 (2022).

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Journal Article

Liu, B.-H., M. Huber, M.A. van Spronsen, M. Salmeron and H. Bluhm: Ambient pressure X-ray photoelectron spectroscopy study of room-temperature oxygen adsorption on Cu(1 0 0) and Cu(1 1 1). Applied Surface Science 583, 152438 (2022).

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Journal Article

Liu, S., A. Hammud, I. Hamada, M. Wolf, M. Müller and T. Kumagai: Nanoscale coherent phonon spectroscopy. Science Advances 8 (42), eabq5682 (2022).

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Journal Article

Loch, P., D. Schuchardt, G. Algara-Siller, P. Markus, K. Ottermann, S. Rosenfeldt, T. Lunkenbein, W. Schwieger, G. Papastavrou and J. Breu: Nematic suspension of a microporous layered silicate obtained by forceless spontaneous delamination via repulsive osmotic swelling for casting high-barrier all-inorganic films. Science Advances 8 (20), eabn9084 (2022).

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Journal Article

Machado, R., M. Dimitrakopoulou, F. Girgsdies, P. Löser, J. Xie, K. Wittich, M. Weber, M. Geske, R. Glaum, A. Karbstein, F. Rosowski, S. Titlbach, K. Skorupska, A. Tarasov, R. Schlögl and S.A. Schunk: Platinum Group Metal-Doped Tungsten Phosphates for Selective C-H Activation of Lower Alkanes. ACS Catalysis 12, 13116–13130 (2022).

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Journal Article

Meunier, F.C., T. Elgayyar, K. Dembélé and H. Kaper: Stability of Pt-Adsorbed CO on Catalysts for Room Temperature-Oxidation of CO. Catalysts 12 (5), 532 (2022).

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Journal Article

Molino, A., M. Hamandi, R. Grosjean, F. Dappozze, L. Lamaa, L. Peruchon, C. Brochier, K. Dembélé, M.E.L. Hajem, P. Vernoux, C. Guillard and H. Kaper: Coupling of photocatalysis and catalysis using an optical fiber textile for room temperature depollution. Chemosphere 297, 133940 (2022).

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Journal Article

Mom, R., L. Falling, O. Kasian, G. Algara-Siller, D. Teschner, R.H. Crabtree, A. Knop-Gericke, K.J.J. Mayrhofer, J. Velasco Vélez and T. Jones: Operando Structure-Activity-Stability Relationship of Iridium Oxides during the Oxygen Evolution Reaction. ACS Catalysis 12 (9), 5174–5184 (2022).

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Journal Article

Mom, R. and A. Knop-Gericke: Hydroxylation of Platinum Surface Oxides Induced by Water Vapor. The Journal of Physical Chemistry Letters 13 (3), 879–883 (2022).

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Journal Article

Narangoda, P., I. Spanos, J. Masa, R. Schlögl and A.R. Zeradjanin: Electrocatalysis Beyond 2020: How to Tune the Preexponential Frequency Factor. ChemElectroChem 9 (4), e202101278 (2022).

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Journal Article

Panafidin, M.A., A.V. Bukhtiyarov, I.P. Prosvirin, I.A. Chetyrin, A. Klyushin, A. Knop-Gericke, N.S. Smirnova, P.V. Markov, I.S. Mashkovsky, Y.V. Zubavichus, A.Y. Stakheev and V.I. Bukhtiyarov: A mild post-synthesis oxidative treatment of Pd-In/HOPG bimetallic catalysts as a tool of their surface structure fine tuning. Applied Surface Science 571, 151350 (2022).

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Journal Article

Papakonstantinou, G., I. Spanos, A.P. Dam, R. Schlögl and K. Sundmacher: Electrochemical evaluation of the de-/re-activation of oxygen evolving Ir oxide. Physical Chemistry Chemical Physics 24 (23), 14579–14591 (2022).

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Journal Article

Plodinec, M., H.C. Nerl, T. Lunkenbein and R. Schlögl: Deactivation Mechanism of Ni Nanoparticles in Dry Reforming of Methane Revealed by Operando TEM. Microscopy and Microanalysis 28 (S1), 146–148 (2022).

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Journal Article

Pollok, C.H., C. Göbel, J.I.S. Gómez, R. Schlögl and H. Ruland: A Gas Generating System for Complex Gas Mixtures – Multifunctional Application in PTR Method Optimization and Downstream Methanol Synthesis. Chemie-Ingenieur-Technik 94 (10), 1438–1451 (2022).

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Journal Article

Reiter, F., M. Pielmeier, A. Vogel, C. Jandl, M. Plodinec, C. Rohner, T. Lunkenbein, K. Nisi, A. Holleitner and T. Nilges: SnBrP-A SnIP-type representative in the Sn-Br-P system. Zeitschrift für anorganische und allgemeine Chemie 648 (10), e202100347 (2022).

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Journal Article

Righi, G., J. Plescher, F. Schmidt, R.K. Campen, S. Fabris, A. Knop-Gericke, R. Schlögl, T. Jones, D. Teschner and S. Piccinin: On the origin of multihole oxygen evolution in haematite photoanodes. Nature Catalysis 5 (10), 888–899 (2022).

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Journal Article

Ripepi, D., B. Izelaar, D.D. van Noordenne, P. Jungbacker, M. Kolen, P. Karanth, D. Cruz, P. Zeller, V. Pérez-Dieste, I.J. Villar-Garcia, W.A. Smith and F.M. Mulder: In Situ Study of Hydrogen Permeable Electrodes for Electrolytic Ammonia Synthesis Using Near Ambient Pressure XPS. ACS Catalysis 12 (21), 13781–13791 (2022).

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Journal Article

Ristig, S., M. Poschmann, J. Folke, O. Gómez-Cápiro, Z. Chen, N. Sanchez-Bastardo, R. Schlögl, S. Heumann and H. Ruland: Ammonia Decomposition in the Process Chain for a Renewable Hydrogen Supply. Chemie-Ingenieur-Technik 94 (10), 1413–1425 (2022).

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Journal Article

Sandoval Diaz, L., R. Schlögl and T. Lunkenbein: Quo Vadis Dry Reforming of Methane?—A Review on Its Chemical, Environmental, and Industrial Prospects. Catalysts 12 (5), 465 (2022).

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Journal Article

Santaya, M., C.E. Jiménez, H.E. Troiani, E. Carbonio, M.D. Arce, L.M. Toscani, R. Garcia-Diez, R.G. Wilks, A. Knop-Gericke, M. Bär and L.V. Mogni: Tracking the nanoparticle exsolution/reoxidation processes of Ni-doped SrTi_0.3Fe_0.7O_3−δ electrodes for intermediate temperature symmetric solid oxide fuel cells. Journal of Materials Chemistry A 10 (29), 15554–15568 (2022).

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Journal Article

Sauer, J., R. Schlögl, A. Trunschke and S.T. Oyama: Foreword. Journal of Catalysis 408, 329–329 (2022).

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Journal Article

Schittkowski, J., B. Zeidler-Fandrich, T. Müller, R. Schlögl and H. Ruland: The Carbon2Chem_® Laboratory in Oberhausen - A Workplace for Lab-Scale Setups within the Cross-Industrial Project. Chemie-Ingenieur-Technik 94 (10), 1397–1404 (2022).

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Journal Article

Schlögl, R.: Chemical Batteries with CO₂. Angewandte Chemie International Edition 61 (7), e202007397 (2022).

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Journal Article

Schlögl, R.: Interfacial catalytic materials; challenge for inorganic synthetic chemistry. Zeitschrift für Naturforschung B 77 (6), 475–485 (2022).

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Journal Article

Schönweger, G., A. Petraru, M.R. Islam, N. Wolff, B. Haas, A. Hammud, C. Koch, L. Kienle, H. Kohlstedt and S. Fichtner: From Fully Strained to Relaxed: Epitaxial Ferroelectric Al_1-xSc_xN for III-N Technology. Advanced Functional Materials 32 (21), 2109632 (2022).

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Journal Article

Sharma, S., H.M. Zeeshan, M. Panahi, Y. Jin, M. Yan, Y. Jin, K. Li, P. Zeller, A. Efimenko, A. Makarova, D. Smirnov, B. Paulus, E. Voloshina and Y. Dedkov: Stability of van der Waals FePX₃ materials (X: S, Se) for water-splitting applications. 2D Materials 10 (1), 014008 (2022).

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Journal Article

Shin, D., S. Bhandari, M.F. Tesch, S.A. Bonke, F. Jaouen, S. Chabbra, C. Pratsch, A. Schnegg and A.K. Mechler: Reduced formation of peroxide and radical species stabilises iron-based hybrid catalysts in polymer electrolyte membrane fuel cells. Journal of Energy Chemistry 65, 433–438 (2022).

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Journal Article

Starr, D.E., M. Hävecker, A. Knop-Gericke, M. Favaro, S. Vadilonga, M. Mertin, G. Reichardt, J.-S. Schmidt, F. Siewert, R. Schulz, J. Viefhaus, C. Jung and R. van de Krol: The Berlin Joint Lab for Electrochemical Interfaces, BElChem: A Facility for In-situ and Operando NAP-XPS and NAP-HAXPES Studies of Electrochemical Interfaces at BESSY II. Synchrotron Radiation News 35 (3), 54–60 (2022).

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Journal Article

Streibel, V., J. Velasco Vélez, D. Teschner, E. Carbonio, A. Knop-Gericke, R. Schlögl and T. Jones: Merging operando and computational X-ray spectroscopies to study the oxygen evolution reaction. Current Opinion in Electrochemistry 35, 101039 (2022).

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Journal Article

Tesch, M.F., S.A. Bonke, R. Golnak, J. Xiao, A.N. Simonov and R. Schlögl: Vacuum compatible flow-cell for high-quality in situ and operando soft X-ray photon-in–photon-out spectroelectrochemical studies of energy materials. Electrochemical Science Advances 2 (6), e2100141 (2022).

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Journal Article

Thum, L., W. Riedel, N. Milojevic, C. Guan, A. Trunschke, K.-P. Dinse, T. Risse, R. Schomäcker and R. Schlögl: Transition-Metal-Doping of CaO as Catalyst for the OCM Reaction, a Reality Check. Frontiers in Chemistry 10, 768426 (2022).

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Journal Article

Tran, H.P., H.N. Nong, H.-S. Oh, M. Klingenhof, M. Kroschel, B. Paul, J. Hübner, D. Teschner and P. Strasser: Catalyst–Support Surface Charge Effects on Structure and Activity of IrNi-Based Oxygen Evolution Reaction Catalysts Deposited on Tin-Oxide Supports. Chemistry of Materials 34 (21), 9350–9363 (2022).

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Journal Article

Trunschke, A.: Prospects and challenges for autonomous catalyst discovery viewed from an experimental perspective. Catalysis Science & Technology 12 (11), 3650–3669 (2022).

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Journal Article

Türk, H., T. Götsch, F. Schmidt, A. Hammud, D. Ivanov, (B.de H. J. L. G., I.C. Vinke, R.-A. Eichel, R. Schlögl, K. Reuter, A. Knop-Gericke, T. Lunkenbein and C. Scheurer: Sr Surface Enrichment in Solid Oxide Cells – Approaching the Limits of EDX Analysis by Multivariate Statistical Analysis and Simulations. ChemCatChem 14 (19), e202200300 (2022).

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Journal Article

Vadilonga, S., P. Dumas, U. Schade, K. Holldack, K. Hinrichs, G. Reichardt, T. Gerber, A. Vollmer, J.P. Hofmann, H. Oertel, B. Rech, R. Schlögl, J. Viefhaus and H. Bluhm: Optical Layout and Endstation Concept for the Enhanced Liquid Interface Spectroscopy and Analysis (ELISA) Beamline at BESSY-II. Synchrotron Radiation News 35 (3), 67–72 (2022).

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